It seems as though Smokey (or whatever/whoever Fake Locke is) can only take the form of dead people. (Locke, Ben's daughter, Ecko's brother, Ben's mom, etc.)
I think the reason Fake Locke kicked Jacob into the fire is because he immediately knew that he would need to take Jacob's form to survive upon hearing Jacob tell him "they're coming". Jacob's body will either be completey burned up or be unrecognizable and Fake Locke will act as though he is the real Jacob(in an incredibly convincing manner) when Alana, Richard and crew arive.
Jacob however, is one step ahead and has already asked Alana to kill him because he knew what was going to happen(he asked her to do so when he went to visit her and she was in bandages). Now that Alana has seen the mimic/doppelganger ability of Fake Locke, she will understand why Jacob asked her to kill him and know that she is not killing the real Jacob.